Enhancing Reductive Cleavage of Aromatic Carboxamides

Synthesis of Zinc Dimethyldithiocarbamate by Reductive Disulfide Bond Cleavage of Tetramethylthiuram Disulfide in Presence of Zn2+

The zinc(II) complex [Zn2(dmdtc)2(μ-dmdtc)2] has been synthesized directly from thiram ligand, containing a disulfide bond {dmdtc = N,N-dimethyldithiocarbamate; thiram = N,N-tetramethylthiuram disulfide}, and characterized by elemental analysis and spectroscopic methods. Surprisingly thiram, undergoes a reductive disulfide bond scission upon reaction with Zn2+ in methanolic media to give the [Z...

Reductive cleavage of disulfide bridges in ribonuclease.

synthesis of zinc dimethyldithiocarbamate by reductive disulfide bond cleavage of tetramethylthiuram disulfide in presence of zn2+

the zinc(ii) complex [zn2(dmdtc)2(μ-dmdtc)2] has been synthesized directly from thiram ligand, containing a disulfide bond {dmdtc = n,n-dimethyldithiocarbamate; thiram = n,n-tetramethylthiuram disulfide}, and characterized by elemental analysis and spectroscopic methods. surprisingly thiram, undergoes a reductive disulfide bond scission upon reaction with zn2+ in methanolic media to give the [z...

Augmentation mammaplasty: enhancing inferomedial cleavage.

BACKGROUND Typically, symmetrical markings are made to lower the inframammary fold (IMF) according to the surgeon's judgment. Because inferomedial fascial attachments of the IMF may at times compromise the proper seating of the implant in this area, causing excessive superior projection, asymmetrical lowering of the IMF is performed to allow for increased lowering of the inferomedial aspect of ...

A convenient reductive deamination (hydrodeamination) of aromatic amines.

Reductive deamination (hydrodeamination) of aromatic amines can be conveniently carried out by amination of the corresponding arylamine methanesulfonamides using chloroamine under alkaline conditions. The intermediate aryl methanesulfonylhydrazines directly eliminate methanesulfinic acid, affording diazenes which extrude nitrogen affording the desired deaminated products. Both sulfonamide forma...